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The History of the Periodic Table.
The periodic
table came about through attempts by people
to group elements according to their chemical
properties.
It is called periodic because similar
chemical properties
of the elements were found to occur at regular
intervals.
What are Dobereiner's Triads?
Dobereiner (1829)
found that some groups of three
elements
that have similar properties, for example lithium,
sodium
and potassium,
the atomic
mass (mass
number) for the
second element was the average of the first
and third element.
For example, lithium has a mass
number of 7 and potassium
has a mass number of 39.
The average is (7 + 39)
÷ 2 = 23.
The
mass number of sodium
is 23.
The same was found for some other groups of three
elements
for example carbon
(12), nitrogen
(14) and oxygen
(16).
These groups became known as Dobereiner's
Triads.
What are Newlands'
Octaves?
John
Newlands (1863) noticed that by
arranging the
elements
in order of
increasing atomic
mass, every eighth element
seemed to have
similar properties. He proposed a similarity with
music, where the eighth note is an
octave
above the first note.
This idea became known as Newlands'
Octaves.
It did not work for the fourth
period with the
transition
metals.
It works for the lighter elements
(atomic number less than
19)
because eight electrons completes the outer shell.
What did Dmitri
Mendeleev do?
Dmitri
Mendeleev is credited as being the Father of the
modern
periodic table. In 1869 he arranged the 50 or so
known elements
in order of atomic
mass, putting elements
with similar properties in the same vertical group, and
leaving gaps for unknown elements, yet
to be discovered.
When the unknown elements were later
discovered, they
were found to have the properties
predicted by Mendeleev's
table.
Knowing nothing of protons, nuclei or atomic number,
Dmitri Mendeleev's periodic table was
broadly correct (genius!).
The modern periodic table is very useful for giving a summary of
the atomic
structure and the electron
structure of all the elements.
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