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How can an Insulator get an Electrostatic Charge?
Insulators can transfer  charge by
friction.
When the surface of one insulator
rubs  
against another,
electrons can be transferred.
The insulator that gains
electrons will get a negative charge,
the insulator that loses electrons will get a positive charge.
It is most
important to know that it is only the negative electrons
which can move.
Positive charges (protons) cannot
move
because they are stuck inside
the nuclei of the
atoms of the material.
For example, if polythene (a
 type of plastic) is rubbed
with a dry cloth,
electrons are transferred from the cloth
to
the polythene.
The polythene gains electrons and
becomes negatively charged,
the cloth loses electrons and
becomes positively charged.
It is not 
possible to predict in advance
which way the
electrons will be transferred for a certain material.
The same cloth, when rubbed against a different
type of
plastic called acetate, will gain electrons and become
negatively charged, leaving the acetate with a
positive charge.
See the GCSE
Chemistry  site
if you want to know more about electrons
and protons.
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