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The Molecular Formula of Compounds.
Example 1.
A compound was found to contain
3·0 g of
carbon and 0·5
g of hydrogen.
The relative molecular
mass of the compound is
42.
What is the molecular
formula of the compound?
Method.
1) Find how many
moles of carbon
react with
how many moles of hydrogen.
RAM of C = 12, RAM of H = 1.
moles = mass ÷ RAM
for carbon
moles = 3
÷ 12
= 0·25 moles.
for hydrogen
moles = 0·5
÷ 1
= 0·5
moles.
2) The proportion of moles
of carbon to moles of hydrogen
is reduced to the lowest whole number.
0·25 moles of C to
0·5 moles of H.
Multiply by 4.
1 mole of C to 2 moles of
H.
The empirical
formula is CH2.
3) Divide
the relative molecular mass of the
compound by
the relative molecular mass of the
empirical formula.
RMM of the compound = 42.
RMM of the empirical formula = RMM of CH2
= 12 + (2 x
1)
= 14.
42 ÷ 14 = 3.
There are
3 CH2 units in the compound.
The molecular formula of the
compound is C3H6.
The compound is propene.
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